Product ID:B65W750 ARMORSEAL ARMOR-PLEX WATER BASED POLYURETHANE PART A
MSDS Date:01/11/1999
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKRKW

Emergency Phone: (216) 566-2917

Info Phone: 216-566-2902

Cage: 86972

Telephone: 216-566-2902/216-566-2917

Cage: 86972

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 10 (5) MG/M3 (DUST)

ACGIH TLV: 10 MG/M3 (TOT DUST)

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ROUTES OF EXPOSURE: EXPOSURE MAY BE BY
INHALATION AND / OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF
USE. TO MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION AND PERSONAL PR OTECTIVE EQUIPMENT. ACUTE HEALTH
HAZARDS (EFFECTS OF OVEREXPOSURE): IRRITATION OF EYES, SKIN AND
UPPER RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN HIGH
CONCENTRATION MAY CAUSE HEADACHE, NAUSEA O R DIZZINESS. CHRONIC:
PERSONS SENSITIVE TO ISOCYANATES WILL EXPERIENCE INCREASED ALLERGIC
REACTION ON REPEATED EXPOSURE. THIS EFFECT MAY BE DELAYED SEVERAL
HOURS AFTER THE EXPOSURE. (SIGNS AND SYMPTO MS OF OVEREXPOSURE)
Explanation of Carcinogenicity:NO INGREDIENT IN PRODUCT IS AN IARC, NTP
OR OSHA LISTED CARCINOGEN. RATS EXPOSED TO TITANIUM DIOXIDE DUST AT
250 MG./M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE
NOT ATTAINABLE IN THE W ORKPLACE.
Effects of Overexposure:HEALTH HAZARDS (CONT): RATS EXPOSED TO TITANIUM
DIOXIDE DUST AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH
EXPOSURE LEVELS ARE NOT ATTAINABLE IN THE WORKSPACE. SIGNS AND
SYMPTOMS OF OVEREXPOSURE: REDNESS AND ITCHING OR BURNING SENSATION
MAY INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS
EFFECT MAY BE DELAYED SEVERAL HOURS AFTER EXPOSURE.

First Aid:IF INHALED: IFANY BREATHING PROBLEMS OCCUR DURING USE, LEAVE
THE AREA AND GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR LATER,
IMMEDAITELY GET MEDICAL ATTENTION. IF ON SKIN: WASH AFFECTED AREA
THOROUGHL Y WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND
LAUNDER BEFORE RE-USE. IF IN EYES: FLUSH EYES WITH LARGE AMOUNTS
OF WATER FOR 15 MINUTES. GET MEDICAL ATTENTION. IF SWALLOWED: GET
MEDICAL ATT ENTION.

Flash Point:NOT APPLICABLE.
Lower Limits:N.A.
Upper Limits:N.A.
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIP INCLUDING (NIOSH
APPROVED) SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO C OOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN
EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. FLAMMABILITY
CLASSIFICATION: NOT APPLICABLE.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:USE ONLY W/ ADEQUATE VENTILATION.
AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/ SKIN AND EYES.
WASH HANDS AFTER USING. DO NOT TAKE INTERNALLY. KEEP CONTAINER
CLOSED WHEN NOT IN USE. TRANSFER ON LY TO APPROVED CONTAINERS W/
COMPLETE & APPROPRIATE LABELING. DOL STORAGE CATEGORY: NOT
APPLICABLE.
Other Precautions:NO PERSON SHOULD USE THIS PROD, OR BE IN THE AREA
WHERE IT IS BEING USED, IF THEY HAVE CHRONIC (LONG-TERM) LUNG OR
BREATHING PROBLEMS OR IF THEY EVER HAD A REACTION TO ISOCYANATES.
THIS PROD MUST BE MIXED WITH OTHER COMPONENTS BEFORE USE. BEFORE
OPENING THE PACKAGES, READ AND FOLLOW WARNING LABELS ON ALL
COMPONENTS.

Respiratory Protection:WHERE OVERSPRAY IS PRESENT, A (NIOSH APPROVED)
POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR SHOULD BE WORN. IF
UNAVAILABLE, A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE RESPIRATOR
APPROVED BY NIOSH FOR PR OTECTION AGAINST MATERIALS IN INGREDIENT
SECTION MAY BE EFFECTIVE. FOLLOW RESPIRATOR MANUFACTURER'S
DIRECTIONS FOR USE. WEAR THE RESPIRATOR FOR (OTHER INFO)
Ventilation:LOCAL EXHAUST IS PREFERABLE. GENERAL EXHAUSTST ACCEPTABLE
IF EXPOSURE IS MAINT BELOW APPLIC EXPOSURE LIMITS. REFER TO OSHA
STD'S 1910.94, 1910.107, 1910.108.
Protective Gloves:WEAR GLOVES WHICH ARE RECOMENDED BY THE SUPPLIER FOR
PROT AGAINST INGREDIENTS.
Eye Protection:ANSI APPROVED CHEMICAL SAFETY GOGGLES .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: KEEP OUT OF THE
REACH OF CHILDREN.
Supplemental Safety and Health
PRODUCT NAME: ARMORSEAL ARMOR-PLEX WATER BASED POLYURETHANE (PART A),
WHITE. PRODUCT CLASS: BASE COMPONENT FOR 2-PACKAGE POLYURETHANE
COATING. PRODUCT WEIGHT: 12.20 LB/GAL. VOC (THEORETICAL): 0.06
LB, 7 GM (LESS FEDERALLY EXEMPT SOLVENTS). HMIS CODES: HEALTH - 1,
FLAMMABILITY - 0, REACTIVITY - 0.

Boiling Pt:=100.C, 212.F
B.P. Text:RANGE 212-213F.
Melt/Freeze Pt:M.P/F.P Text:N.A.
Vapor Density:> THAN AIR
Spec Gravity:1.47
pH:7.0
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:N.A.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER, MSDS SUGGESTS:
WHITE LIQUID .
Percent Volatiles by Volume:50%

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM THIS PRODUCT IS NOT HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE CLOSED
CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS REGARDING POLLUTION.

Toxicological Information:THIS COATING MAY CONTAIN MATERIALS CLASSIFIED
AS NUISANCE PARTICULTES WHICH MAY BE PRESENT AT HAZARDOUS LEVELS
ONLY DURING SANDING OR ABRADING OF THE DRIED FILM. THE APPLICABLE
LIMITS FOR NUISANCE DUS TS ARE ACGIH TLV 10 MG./M3 (TOTAL DUST), 3
MG./M3 (RESPIRABLE FRACTION). OSHA PEL 15 MG./M3 (TOTAL DUST), 5
MG./M3 (RESPIRABLE FRACTION).

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:NO INGREDIENTS IN THIS PRODUCT ARE SUBJECT
TO SARA 313 (40 CFR 372.65C) SUPPLIER NOTIFICATION.
Federal Regulatory Information:ALL CHEMICALS IN THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. WASTE
FROM THIS PRODUCT IS NOT HAZARDOUS AS DEFINED UNDER THE RESOURCE
CONSERVATION AND RECOVERY ACT (RCR A) 40 CFR 261.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.